Power Sources. Research and Development in Non-Mechanical by D. H. Collins

By D. H. Collins

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REFERENCES 1. 2. 3. 4. 5. 6. 7. 8. 9. KRYUKOVA, T. A. Soviet Electrochemistry, Vol. I l l , p. 147. ROMANOV, V. V. Zhur. Priklad Khim 36, 5, 1050 (1963). ROMANOV, V. V. Zhur. Priklad Khim 35, 1293 (1962). ROMANOV, V. V. R. Pat. 141,187 (1961). HARNED, H. S. and OWEN, B. B. Physical Chemistry of Electrolytic Solutions, Chapt. 14, 2nd Ed. Reinhold. OXLEY, J . E. The Improvement of Zinc Electrodes for Electrochemical Cells. Final Report. Prepared for Goddard Space Flight Center under Contract NAS5-3908.

Wright Patterson Air Force Base. OXLEY, J . E. The Improvement of Zinc Electrodes for Electrochemical Cells NASA CR377. Prepared for Goddard Space Flight Center under Contract NAS5-3873. DISCUSSION G. D. NAGY (Defence Research Laboratories, Canada) : We have observed differences in concentrations of zincate at the top and bottom of vertical cells. Were any differences in the gradients observed at different levels of the vertical dimension of the separator ? In other words, is it not necessary to also consider any vertical gradient that may be set up in the separator ?

This hypothesis being admitted the linear relation found between the manganese dioxide potential and the oxidation degree xy E = 0·56#— 1, may be given a theoretical explanation. The determination of dE/dx, which in this case does not much differ from dE°/dx, actually gives a value (0*56) very near to that found by Bode in different conditions. e. from x = 1·75), y-manganese dioxide being progressively transformed to y M n 2 0 3 , an electrochemical reaction of the following type may be written : 2MnO r 6 (OH) 0 .

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